transition metal clusters in the gas-phase, typically in the size range of 3 to more than 20 atoms, empha-sizing specifically the insights gained from vibrational spectroscopy. Please check your email for instructions on resetting your password. Working off-campus? �;��� ?���O��I_� $��z�O|~xq�3-�P�?W���[�8}l>��no~���cK˸"����O���%��\�Ɏ��Ňz�#tw�ٙ�\0ϥvUd�0!��f��,�f �M+ۡ�*uDz&�,�)�YΥ�Sv�\MY�P�CB� ���;y���}��oǀ=ǔ�ڂub�c��s�0��ی��*i3fO6�/�&�p�c˶��۴�����04v GBS���X�O�Lew4�����K_W�v�-����kqE�3���}~�\��Hv����D{働U��'�>Ѳ�Kq���/5>��j��w�/M�[�|�Iω��hz?����5��"�l���2�����'4��lne���T6p���U? Unlimited viewing of the article PDF and any associated supplements and figures. If you have previously obtained access with your personal account, please log in. December 1997; New Journal of Chemistry 22(7) DOI: 10.1039/A709249K. Learn more. This Minireview summarizes the recent advances in 3d metal cluster photocatalysts with well‐defined structures for photocatalytic water splitting and focuses on different clusters with tunable structures that are capable of achieving better photocatalytic properties. Rev. The catalytic core of photosynthetic enzymes is a cubic CaMn 4 O 5 cluster. Water splitting based on first‐row transition metal (3d) photocatalysts is a cost‐effective technology for the conversion of abundant solar energy into useful energy on a large scale. %PDF-1.4
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