Bicine Determination by Ion Chromatography This paper explores the conditions which lead to bicine production in MDEA-based solvents based on new laboratory results, and presents pathways which explain its formation. The majority of refinery cyanides are formed in the reactor of fluid catalytic cracking (FCC) units. Bicine has been shown to form in amine systems utilising MDEA-based amines when subjected to O2 contamination. Bicine can be determined using cation exchange chromatography with electrochemical detection. Crambeth Allen Publishing Ltd, Instrumentation, Automation and Process Control. ABSTRACT Bicine, N-N-bis(2-hydroxyethyl)glycine CAS# 150-25-4, has been identified as a contaminant in amine gas treating solutions.                 /      T. Kudo, et al., A simple and improved method to generate human hybridomas. This website uses cookies to ensure you get the best experience on our website. However, Bicine is a strong chelator with iron and can initiate, in the presence of H2S, a fast acting corrosion mechanism. Imines are typically prepared by the condensation of ammonia or primary amines with aldehydes and ketones. The entire process is very energy intensive and results in high operating costs. The sulfur plant uses oxygen from air that is pumped into Our dedicated research and development group continues to make improvements in our technologies meeting the challenges ... MPR Services understands that amine engineers face a never ending group of challenges in ensuring their systems perform as designed. Using chemical analysis to diagnose amine upsets. 14859 East Clark Avenue var CurrentYear = new Date().getFullYear() Bicines (bicine and other similar amino acids) are formed in amine gas treating systems as a result of amine degradation due to the presence of oxygen and/or sulfur dioxide. Bicine is a very corrosive degradation product produced in certain DEA and MDEA systems. Regardless of the actual formation mechanism, the bicine formation reaction can be generally described as: Understanding the link between the analysis report and the amine system operation can be foggy. 4/1/2009 4:00 AM, Weck Laboratories, Inc. - Designed and Developed at Weck Laboratories, Inc. Gary L Lawson, Arthur L Cummings and Shade Mecum W. J. Ferguson, et al., Hydrogen ion buffers for biological research. Bicine The presence of Bicine alone in the amine system is not necessarily corrosive. 6. Biochemistry. City of Industry, CA 91745, Tel: (626)336-2139 document.write(CurrentYear) Amine system operators must take steps to minimize O2 and SO2 incursion into the amine system and will need to monitor Heat Stable Salts and Amino Acids (Bicine) concentrations in the amine. The alkalinity of gas washing solutions containing alkanolamines is measured by potentiometric titration with sulphuric acid using a combined glass electrode. The diffusion coefficients of CO2 in the aqueous amino acid salt solutions can be estimated by means of the N2O analogy. Amine system operators must take steps to minimize O2 and SO2 incursion into the amine system and will need to monitor Heat Stable Salts and Amino Acids (Bicine) concentrations in the amine. Nucleation kinetics of glycine promoted concentrated potassium carbonate solvents for carbon dioxide... Diffusivities in Aqueous Solutions of the Potassium Salt of Amino Acids. Bicine has been shown to form in amine systems utilising MDEA-based amines when subjected to O2 contamination. Without a clear understanding of those conditions, bicine production will continue to be a problem for natural gas conditioning and refinery based amine solvent systems. . By implementing Metrohm’s fully automated online monitoring solution for this process, it is possible to optimize the amine activity and measure the efficiency of the acidic gas capture, reducing overall costs while ensuring environmental compliance. The corrosion probe was placed in the 250°F “reboiler” section. Bicine by itself in an amine solution is not corrosive to carbon steel. S2O3 + MDEA + heat + time   --- Formate 1990;116:65-77. Amine gas sweetening is a proven technology that removes H₂S and CO₂ from natural gas and liquid hydrocarbon streams through absorption and chemical reaction. 626-336-2139 | Most biological reactions occur at a neutral pH, from 6 to 8; the buffer needs to be effective in this range. This paper aims to address the points where MEG has … The proposed pathways for the formation of bicine in amine solutions are all from alkanolamines and alkylalkanolamines such as DEA and MDEA. ... Bicine, ULTROL Grade - CAS 150-25-4 - Calbiochem CAS Number: 150-25-4. 1971;17:651-653. Buffers, mixtures of appropriate weak acids, and their conjugate bases, are usually used. dm-3. Fax: (626)336-2634, Mon-Fri: 8:00A-5:30P Problems resulting from corrosion, foaming and loss of acid gas absorption arise from processing with contaminated amine/glycol. 3) Consistent acid-base dissociation constants Experimental Studies on Carbon Dioxide Absorption using Potassium Carbonate Solutions with Amino Aci... A new amine, stizolamine, from Stizolobium hassjoo. Can J Microbiol. Corrosion in alkanolamine gas treating solutions begins with the acid gases which are the target of the treating, and is enhanced by several physical and chemical factors. The diffusivities can be estimated with sufficient accuracy using a modified Stokes-Einstein relation. 1966;5:467-477. . Download Citation | The Relevance of Bicine in Corrosion of Amine Gas Treating Plants | Bicine, N,N-bis(2-hydroxyethyl)glycine, has been identified as a contaminant in amine gas treating solutions. It is prepared by the reaction of glycine with ethylene oxide, followed by hydrolysis of the resultant lactone. 1971;233:271-273. Anal Biochem. Chemical Name: N,N-Bis(2-hydroxyethyl)glycine Copyright (c) 2020 Weck Laboratories, Inc. Food, Beverage, Pharmaceutical & Dietary Supplements, ANSI-ASQ National Accreditation Board (ANAB) ISO 17025:2005, State of California Department of General Services Small Business Certification. Through both laboratory analytical studies and numerous full scale “in plant” Bicine removal projects, it has been demonstrated that amine system corrosion can be reduced when the amine system is cleaned by ion exchange through the removal of Bicine and the precursors of Bicine.

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